Breakthroughs

The bio-based material that’s stronger than spider silk

KTH Royal Institute of Technology
The material created by KTH Royal Institute has a tensile strength of 1.57 gigapascals, stronger than dragline spider silk fibers.

Companies seeking viable, scalable alternatives to the composites or metals used as the backbone of automotive and aviation parts should keep their eyes on a biomaterials project being spearheaded by Sweden’s oldest technical university, KTH Royal Institute of Technology.

Early this year, researchers there revealed that they had engineered a cellulose nanofiber — aka the building block of trees and plants — described as eight times stiffer and 20 percent stronger than spider silk, commonly considered the world’s strongest biologically derived substance. For those who like data: It has a tensile strength of 1.57 gigapascals; spider silk ranges from 0.6 to 1.3 GPa.

The lightweight material could have applications in a variety of sectors from automotive to aviation parts to furniture to medical devices such as artificial joints (although the latter uses will take longer to emerge), according to Daniel Soderberg, one of the KTH researchers. It could be used to replace some metal, alloys or ceramics, helping manufacturing address and reduce the carbon emissions typically associated with the production of those materials.

"One of the biggest challenges in fabricating engineering materials — materials that can be used to make ‘real products’ for society — from nanocomponents is to make use of the often-exceptional properties of the nanoscale building blocks in such a manner that the engineering material is able to retain these properties," Soderberg wrote in an email, in response to my questions about the project.

"In our work, we have successfully been able to take one such nanocomponent, i.e. nanocellulose, which is nature’s high-performance building block made by evolution to build e.g. trees and plants to make a usable … material that has exceptional mechanical properties on par with the performance of the nanocomponent."

How they did it

The researchers created the material using existing commercially available nanofibers from spruce and pine trees. It’s actually a mashup of multiple fibers: a series of individual fibers — each measuring about 2-5 nanometers in diameter and up to 700 nm long — is packed together by suspending them in deionized and low pH water in a 1-millimeter, stainless steel channel. This allows "supranuclear interactions" that join the individual strands together.

KTH Royal Institute
The nanofibers are squeezed together using a process called "hydrodynamic focusing."

The researchers got their inspiration from nature: by studying the alignment of the outer cell walls of trees and how they bond together. (You know, the ones that help them maintain their structure, even when they reach heights of 100 feet or taller.) You can read more specifics in this technical article co-authored by Soderberg that describes the research. 

What’s the drawback? One of Soderberg’s co-authors, Nitesh Mittal, told Chemical & Engineering News that humidity could affect the performance of the nanofibers and weaken them. That means the cellulose nanofiber must be combined with other biobased materials to be truly practical. 

One of the largest objections to biomaterials is the perceived expenses associated with migrating to new manufacturing or operational processes. Based on what’s known today, the production process for this biomaterial would carry costs on a par with creating Kevlar fibers, Soderberg wrote in response to another question.

The KTH team is working with RISE Bioeconomy, another Swedish research organization, on an effort to produce larger quantities of the material in order to test it in practical applications. The researchers expect to receive a patent for their process by October, which will guide the next steps toward commercialization.  

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