Turning methane into carbon dioxide could help us fight climate change
Discussions on how to address climate change have focused, very appropriately, on reducing greenhouse gas emissions, particularly those of carbon dioxide, the major contributor to climate change and a long-lived greenhouse gas. Reducing emissions should remain the paramount climate goal.
However, greenhouse gas emissions have been increasing for two centuries. Damage to the atmosphere is already profound enough that reducing emissions alone won’t be enough to avoid effects such as extreme weather and changing weather patterns.
In a paper published this week in Nature Sustainability, we propose a new technique to clean the atmosphere of the second most powerful greenhouse gas people produce: methane. The technique could restore the concentration of methane to levels found before the Industrial Revolution, and in doing so, reduce global warming by one-sixth.
Our new technique sounds paradoxical at first: Turning methane into carbon dioxide. It’s a concept at this stage, and won’t be cheap, but it would add to the tool kit needed to tackle climate change.
The methane menace
After carbon dioxide, methane is the second most important greenhouse gas leading to human-induced climate change. Methane packs a climate punch: It is 84 times more powerful than carbon dioxide in warming the planet over the first 20 years of its molecular life.
Methane emissions from human activities are larger than all natural sources combined. Agriculture and energy production generate most of them, including emissions from cattle, rice paddies and oil and gas wells.
The result is methane concentrations in the atmosphere have increased by 150 percent from pre-industrial times, and continue to grow. Finding ways to reduce or remove methane therefore will have an outsize and fast-acting effect in the fight against climate change.
What we propose
The single biggest challenge for removing methane from the atmosphere is its low concentration, only about 2 parts per million. In contrast, carbon dioxide is at 415 parts per million, roughly 200 times higher. Both gases are much more diluted in air than when found in the exhaust of a car or in a cow’s burp, and both would be better served by keeping them out of the atmosphere to start with.
Nonetheless, emissions continue. What if we could capture the methane after its release and convert it into something less damaging to climate?
That is why our paper proposes removing all methane in the atmosphere produced by human activities — by oxidizing it to carbon dioxide. Such an approach has not been proposed before; previously, all removal techniques have only been applied to carbon dioxide.
This is the equivalent of turning 3.2 billion metric tons of methane into 8.2 billion metric tons of carbon dioxide (equivalent to several months of global emissions). The surprising aspect to this trade is that it would reduce global warming by 15 percent, because methane is so much more warming than carbon dioxide.
This reaction yields energy rather than requires it. It does require a catalyst, though, such as a metal, that converts methane from the air and turns it into carbon dioxide.
One fit-for-purpose family of catalysts are zeolites. They are crystalline materials that consist of aluminum, silicon and oxygen, with a very porous molecular structure that can act as a sponge to soak up methane.
They are well known to industrial researchers trying to oxidize methane to methanol, a valuable chemical feedstock.
We envision arrays of electric fans powered by renewable energy to force large volumes of air into chambers, where the catalyst is exposed to air. The catalyst is then heated in oxygen to form and release CO2. Such arrays of fans could be placed anywhere where renewable energy — and enough space — is available.
We calculate that with removal costs per metric ton of CO2 rising quickly from $50 to $500 or more this century, consistent with mitigation scenarios that keep global warming below 2 degrees Celsius, this technique could be economically feasible and even profitable.
We won’t know for sure, though, until future research highlights the precise chemistry and industrial infrastructure needed.
Beyond the clean-up we propose here, methane removal and atmospheric restoration could be an extra tool in humanity’s belt as we aim for stringent climate targets, while providing new economic opportunities.
Future research and development will determine the technical and economic feasibility of methane removal. Even if successful, methane- and other carbon-removal technologies are no substitute for strong and rapid emissions reductions if we are to avoid the worst impacts of global warming.
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